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From corn to flake: Health-promoting phenolic acids lost during food processing

In a set of recent studies, scientists revealled what happens to cancer-fighting phenolic acids in corn when it is processed into cornflakes.

Phenolic acids

CORN FLAWS: Corn loses its health-promoting phenolic compounds during processing into corn flakes, according to new research from the University of Illinois

In a Journal of Agricultural and Food Chemistry study, the research team from the University of Illinois made cornflakes from 19 corn genotypes varying in phenolic content.

They wanted to know if higher ferulic acid and p-courmaric acid content in the corn kernel translated to higher concentrations of these phenolics in the final product.

“What we found was not particularly good news, but it was interesting. Regardless of the concentration in the grain at the beginning, the dry-milling process removes the majority of phenolics,” said Dr Carrie Butts-Wilmsmeyer, lead author of the two studies and Research Assistant Professor in the Department of Crop Sciences at U of I.

The phenolic compounds in corn are primarily concentrated in the bran, or the outer covering of the corn kernel, which is removed in the first steps of the dry-milling process.

The researchers wanted to determine if they could increase the remaining soluble phenolic content by heating the starchy leftovers during later processing stages.

Although most of the phenolics in corn are bound to fibre, heat can release bound forms of the compounds and improve the antioxidant content of corn-based foods.

“We did see an increase in soluble phenolics, but it was so small, you could have gotten the same benefit from going to the refrigerator and eating a few blueberries,” Dr Butts-Wilmsmeyer said.

Despite the less-than-ideal outcome, the studies represent important steps forward for food science researchers and the food processing industry. First, the lab-bench-size process developed and demonstrated by the researchers in the Journal of Visualized Experiment sallows testing of small batches of experimental corn lines.

“Before this project, the only published study on cornflake processing used a sample size of 45 kilograms. We worked with ag engineers to get it down to 100 grams, literally a 450th of the size,” Dr Butts-Wilmsmeyer added.

They found that the biggest changes in phenolic content were happening at three stages of the dry-milling process: whole kernel, flaking grit, and toasted cornflake.

“Since we now have the process miniaturised and can control everything in the lab, we can also start figuring out how we can change the process to recover more of these compounds in the end product,” said Martin Bohn, co-author of the studies and Associate Professor in the Department of Crop Sciences at U of I.

Although the phenolics didn’t make it to the final product, they weren’t lost entirely.

“We have to focus on the bran and other ‘waste’ products,” Professor Bohn said. “Is it possible to extract these compounds and fortify the food with them? This is what I think is important.

“Our study showed that at the beginning, there’s variability in corn hybrids for all these compounds but through processing, it’s all levelled off, it’s all gone. But they’re still in the co-products, and I think we could actually recover them and add them to the end product.”

Dr Butts-Wilmsmeyer said fortifying processed foods with health-promoting, cancer-fighting phenolics could benefit people without easy access to fresh foods, such as Americans living in food deserts.

Both studies were supported by the Kellogg Company and Dow AgroSciences and through a USDA Hatch Grant.

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